Product ID:CERAMIC REPAIR HARDENER, 11700
MSDS Date:06/15/1992
FSC:8030
NIIN:00N037681
Kit Part:Y
MSDS Number: BQVBM

ITW DEVCON CORP

30 ENDICOTT ST
DANVERS, MA 01923
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 508-777-1100

Cage: EO352

ITW PHILADELPHIA RESINS

MONTGOMERYVILLE, PA 18936 US

Telephone: 215-855-8450

Cage: 20420

MANNICH-BASE ADDUCT OF TRIETHYLENE TETRAMINE & PHENOL

Fraction By Weight: 30-60%

PHENOL

CAS: 108-95-2

RTECS: SJ3325000

Fraction By Weight: 5-10%

OSHA PEL 5 PPM, S

ACGIH TLV: 5 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TRIETHYLENETETRAMINE

CAS: 112-24-3

RTECS: YE6650000

Fraction By Weight: 10-30%

LD50 LC50 Mixture:LD50:(ORAL,RAT)414 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYES:CAN CAUSE SEV IRRIT & POSS
PERM EYE DAM. SKIN:SEV IRRIT/BURNS. PHENOL CAN BE ABSORBED THRU
SKIN; SYMPS INCL SKIN BLEACHING, HDCH, WEAK, SHALLOW BREATH. INHAL:
UNLIKELY UNLESS MATL IS HEATED /ATOMIZED; HIGH VAP CONC CAN CAUSE
SEV RESP IRRIT. INGEST: LIKELY TO CAUSE SEVERE DAMAGE (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:TO MUC MEMB; INGESTED PHENOL CAN DAM
LUNGS, LIVER, SPLEEN, KIDNEYS, PANCREAS, CNS. CHRONIC: PRLNGD/RPTD
OVEREXP CAN CAUSE SKIN/RESP SENSIT, W/SKIN SYMPS SUCH AS ITCH,
SWELL/RASHES, &/OR ASTHM A-LIKE RESPONSES ON LATER EXPOSURE.
CHRONIC OVEREXPOSURE TO PHENOL CAN HARM SKIN, DIGESTIVE SYS, & NERV
SYS (CNS).
Medical Cond Aggravated by Exposure:ALLERGIES, ECZEMA, AND OTHER SKIN
DISORDERS.

First Aid:EYES: FLUSH W/CLEAN WATER FOR @ LST 15 MIN WHILE GENTLY
HOLDING LIDS OPEN. GET IMMED MED ATTN. SKIN: IMMED REMOVE CONTAMD
CLTHG; WASH THORO W/MILD SOAP & WARM WATER. CONSULT A PHYS IF IRRIT
DEVELOPS. INHAL: REMOVE TO FRESH AIR. ADMINISTER OXYGEN IF BRTHG
IS DFCLT. GET MED ATTN. INGEST: CORR-DO NOT INDUCE VOMIT. IF
CONSCIOUS, GIVE LG AMTS OF WATER/MILK. GET IMMED MED HELP.

Flash Point Method:PMCC
Flash Point:>250F,>121C
Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:TOXIC FUMES WILL BE RELEASED WHEN THIS
MATERIAL BURNS OR IS THERMALLY DECOMPOSED.

Spill Release Procedures:PREVENT SKIN AND EYE CONTACT. REMOVE
CONTAMINATED CLOTHING; DISCARD CONTAMINATED LEATHER ARTICLES SUCH
AS SHOES/BELTS. ABSORB SPILL ON INERT MATERIAL SUCH AS VERMICULITE,
AND TRANSFER TO IMPERVIOUS CO NTAINERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE WELL-CLSD IN A COOL, DRY PLACE.
CONTAMD CLTHG & PROT GEAR SHOULD BE REMOVED & CLEANED BEFORE
RE-USE. KEEP HANDS AWAY FROM EYES WHEN HNDLG MATL.
Other Precautions:PRLNGD/RPTD OVEREXP MAY CAUSE SENSIT, W/ALLERGIC
RESPONSE ON LATER EXPOS. THOSE SO AFFECTED SHOULD CONSULT A PHYS, &
AVOID FURTHER EXPOS TO MATL IF SENSIT IS CONFIRMED. TAKE PROPER
PREC AGAINST OVEREX P TO DUST THAT MAY BE (SUPP DATA)

Respiratory Protection:NONE REQUIRED IN NORMAL USE WITH GOOD
VENTILATION; IN POORLY VENTILATED AREAS, WEAR NIOSH/MSHA APPROVED
ORGANIC VAPOR MASK.
Ventilation:LOC EXHAUST IS RECOM FOR CONFINED AREAS & FOR PRLNGD/RPTD
USE OF PRODUCT. GEN MEC VENT IS ADEQ FOR NORMAL USE.
Protective Gloves:CHEMICAL RESISTANT RUBBER GLOVES.
Eye Protection:SAFETY GLASSES WITH SIDE SHIELDS.
Other Protective Equipment:OTHER PROTECTIVE GEAR. EMERGENCY EYE BATH &
DELUGE SHOWER .
Work Hygienic Practices:CONTAMD CLTHG & PROT GEAR SHOULD BE REMOVED &
CLEANED BEFORE RE-USE. CONTAMD LEATHER ARTICLES CANNOT BE (SUPP
DATA)
Supplemental Safety and Health
PH: 10.5-11(5% BY WT). OTHER PREC: GENERATED FROM SANDING/MACHINING
CURED MATERIAL. HYGIENE PRACT: DECONTAMD & SHOULD BE DISCARDED.
WASH THORO AFTER USING IT, ESP BEFORE EAT/SMOKING.

Vapor Pres:<1
Spec Gravity:1.09
pH:SUPDAT
Evaporation Rate & Reference:<1(BUTYL ACETATE=1)
Solubility in Water:APPRECIABLE
Appearance and Odor:OFF-WHITE PASTE WITH PHENOLIC ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ACIDS, AND CHLORINATED ORGANIC COMPOUNDS.
Stability Condition to Avoid:EXPOSURE TO OPEN FLAME/EXTREME HEAT.
Hazardous Decomposition Products:OXIDES OF NITROGEN AND CARBON;
AMMONIA.
Conditions to Avoid Polymerization:HEAT IS RELEASED WHEN THIS MATERIAL
IS MIXED W/EPOXY RESIN; BE CAREFUL WHEN MIXING A POUND OR MORE.

Waste Disposal Methods:TREAT AS HAZARDOUS WASTE IN COMPLIANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.